Prepping for An Unexpected Power Outage. You don’t have to be a prepper to realize that power outages can happen anytime, to anybody, and anywhere. Some outages are planned, some are the result of Mother Nature kicking up a storm, and some are the unexpected result of a natural or man- made crisis. More recently, the threat of a cyber- attack or terrorist invoked EMP has been added to the mix, and most assuredly, if that were to happen, we will be without power for an extended time. The bottom line is this: the delicacy of our grid is such that nearly any disruption can cause a sudden and unexpected power outage. Whatever the reason, there are various measures you should take now to ensure both your comfort and safety when the power blows unexpectedly. The good news is that prepper or not, most people already have the most basic power outage survival items on hand: Flashlights. Batteries. Candles. ![]() Matches. Blankets. Unless you have been living in a cocoon in Siberia, chances are that these items have already been set aside in your household so that they will be readily available when the lights blink off. For a 3- or 4- hour outage, you will be just fine with these basic supplies. But what if the power is lost for a longer period of time? How will you cook your food? How will you keep warm? How will you ensure your safety and security in the dark? These are just a few of the issues you will face if there is an unexpected and extended power outage. Add infants, the elderly, or the infirm to the mix unless you have planned ahead, you will have a big problem and potential catastrophe on your hands. Preparing in Advance For a Power Outage. · Security. Let's face it. Software has holes. And hackers love to exploit them. New vulnerabilities appear almost daily. If you have software - we all do - you need to.![]() Today I get back to survival basics and offer suggestions and ideas for prepping for an unexpected power outage. My goal is to get those wheels in your brain cranking, and to provide you with a list of suggestions that can be implemented in stages as your needs and budget allow. Store foods that require very little in terms of warming or cooking. These foods should be items that your family normally eats. Suggestions? Canned meats, peanut butter, crackers, canned fruits and veggies granola bars, and cold cereals. If you are a coffee drinker, include some instant coffee as well. The list is endless but let me caution you: if you gag at the thought of cold ravioli out of a can now, you will also gag if you have to eat it in an emergency, power outage situation. Don’t be silly. Store foods that are meant to be eaten cold or at room temperature, or, if not, try sampling them in advance just to be sure. This may sound crazy but cold baked beans out of a can are actually quite good! Don’t forget the manual can opener and some disposable plates and utensils. ![]() Acquire one or more alternate cooking sources. You can cook outdoors using a fire pit, charcoal or propane barbeque, camp stove or even a DIY rocket stove. We are lucky in that we have a propane cooktop in our kitchen that can easily be lit with a match. In addition, we have a Volcano Collapsible Cook Stove, an Eco. Zoom rocket stove, and three Solo Stoves. These devices provide options when it comes to using fuel not the least of which is biomass. We also have a cast iron fire pit that is set up for cooking, a couple of butane stoves, a gas grill, and a Sun Oven. Store fuel for your chosen cooking method. Except for the Sun Oven, all require a source of fuel so don’t overlook having a supply on hand lest you take to chopping up the furniture to fuel the campfire. This could be wood for the fire pit, propane cylinders for the gas grill, or 1. WinUAE 3.4.0 released (21.12.2016) New emulated hardware: Graphics adapters: ColorBurst; Harlequin; OpalVision (OpalPaint, King of Karate) Accelerator boards. 4218 extensions de fichiers, mise à jour le 20/05/2001. It could also be a large bucket of pine cones or twigs to use as biomass in your rocket stove. The point is to store fuel because without question, you are going to need it. One more point: educate yourself on the proper storage of fuel. All of the food in the world will not help you one bit if you blow yourself to bits with fuel that has not be stored and used in a safe manner. If propane is your fuel of choice, you will find lots of information and useful tips in the series Propane For Preppers, The Five Part Series. Have at least one good lantern plus lots of flashlights. Choose a lantern that will cast a wide beam and one that is large enough to fill a room with brightness when the sun goes down. We have both a Coleman propane lantern and a Coleman battery powered lantern. Coleman lanterns are a timeless choice because they last forever and replacement parts, even for older models, are readily available. Solar lanterns are also useful and these days, many can be charged when the skies are overcast? My favorite is the Sun Bell which can also be used to charge a cell phone, Kindle, or other electronic device. Then there are flashlights. Although they are pocket- sized, you can’t beat the price on these Mini- Crees (usually less than $4), the Coast HP1, and the Block- Lite. All right, I do have a flashlight fetish and just can’t help myself! Stock supplies for bundling up. Blankets are good, but a nice toasty sleeping bag or down comforter is better. A heavy jacket and socks are good, too. Plan to add layers for staying warm in a grid down scenario. Long johns, covered by clothing and topped with a jacket will serve you well. Don’t forget hats, scarves, and fingerless gloves, so that you can stay warm and still function. Invest in a generator. We invested in a 1. Think it won’t happen to you? A number of years back, the city of Seattle was dark for almost a week. It happens. After Superstorm Sandy hit the East Coast a few years ago, the power was down for weeks in parts of New York City. I am not suggesting that you invest thousands of dollars in a whole house generator, For one, they take a lot of fuel. Also, installation by a qualified electrician is probably going to cost as much as the generator itself. If you do go this route, make sure you test the installation! I can not stress this too much. After having my own generator installed, I was caught with no refrigerator power during a short term outage because I stupidly trusted the electrician to get things right. Wrong. The wiring from the refrigerator to the master panel was not connected and we lost of lot of food, Whatever you do, test then test again every few months or so. A portable generator can be purchased for as little as $5. If I were to do this again, I would skip the big, expensive unit and go with a portable unit. Rather than rely on a generator for power, I would much rather have the skill and determination to live without power for the duration of the outage. There is one more caveat with generators. They can alert criminals that you are well prepared. Some generators are quite noisy, and your home will be a beacon in the darkness if it’s the only one lit up during an emergency. Depending where you live, caution is advised. The last point that I want to make again lest you forget: be sure that you store plenty of fuel for your generator. Consider solar power. If you have the proper sun exposure, the budget, and the space, solar power can be a backup to your local power grid. Many local utilities, states, and even the federal government offer financial incentives and policies that promote renewable energy. It is worth checking into. Fill empty milk or juice jugs with water then store them in your freezer so that all of the spare nooks and crannies are filled. This will serve a variety of purposes, The freezer will operate more efficiently because it is full, plus, if there is an outage, the frozen jugs of ice will hold the contents cool for a longer period of time. You can even move some of the jugs of ice to your refrigerator to keep things cold for a short term following an unexpected outage. Note: the water stored in this manner, when thawed, can be used for cleaning or flushing but not for drinking unless it is purified or filtered. For more help understanding how to keep food safe during a power outage, read 1. Tips for Keeping Food Safe When the Power Goes Out. Other Useful Stuff. We have covered basic power needs but what are some of the other essentials that you will want to have on hand during a power outage? The following items will help you to sail through a power outage: Battery operated or hand crank radio. Remember, without power, there may be no way to use your computers. Your DSL or cable service is likely to be kaput at well. This could be the only way you are able to get news. Win. UAE Amiga emulator. Win. UAE 3. 4. 0 released (2. New emulated hardware: Graphics adapters: Color. Burst. Harlequin. Opal. Vision (Opal. Paint, King of Karate)Accelerator boards: Blizzard 1. MK II and III. IVS Vector 6. HD controllers: Blizzard 1. MK II and III SCSI Kit. Buddha. Expansion Systems Dataflyer Plus. File. Card 2. 00. OSSI 5. 00. Mainhattan A- Team. Microbotics Hard. Frame. SCRAM 5. 00/2. Network adapters: Amiga. Net. Ariadne. Ariadne II. LAN Rover/EB9. 20. NE2. 00. 0 compatible PCMCIA. NE2. 00. 0 compatible ISA (x. X- Surf and X- Surf 1. Partial). American Laser Games arcade game hardware: Laser. Disc player (video file)Genlock (using video file genlock mode)Light gun and buttons. New features: RAM/RTG RAM handling updated, all size combinations are now supported. Autoconfig board GUI list with custom sorting support. RAM Z2/Z3 board full autoconfig data customization support. Up to 4 Z2 and Z3 RAM boards can be enabled simultaneously. Multiple display and sound boards can be now enabled simultaneously. Genlock realtime custom image, video file or capture stream overlay. Genlock mode screenshot/video alpha channel support. Accelerator board 6. Game Ports panel custom mapping autofire support. Network access on screen led. Single step (emulate one frame + pause) input event. MIDI and Genlock video volume control. Updates: Reduced input latency. Reduced WASAPI sound mode latency. Win. PCap network mode now uses generated local MAC address, no more MAC conflicts between Windows and emulated Amiga. If some RAM board is not JIT Direct capable, only board’s access mode changes to JIT Indirect. Global JIT Direct option is not switched off. Most RAM size/position related JIT Direct restrictions are gone. Environment variables in file paths (%VAR%) are now always expanded. Implemented AGA only bitplane DMA overrun emulation (Moon Child). Host path 2. 60 character limit removed (Windows 1. Bug fixes: Shortcuts with Shift key work again. Custom Game Port remapping does not disappear mysteriously anymore. Mounting file with size less than 5. CDTV statefiles fixed. On the fly directory/archive mounting only worked once under OS4. Worms DC and ACSYS (possibly others) graphics glitch fixed. Bad sprite collision optimization fixed (Jumpman Junior). Stop PPC emulation first, before freeing any emulation resources to prevent random crashes at exit. FPS. Adj config file handling fixed. ATAPI CD emulation odd data size fix (HDToolbox hang)default.
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![]() The Best Video Game Handguns. If you’ve played video games, you’ve encountered a handgun. In the right game, a handgun can be an object of menace or empowerment. But video games often treat them as a starter weapon to be replaced as soon as possible. What makes for a great video game handgun? A Brief History Lesson. Handguns are among the oldest type of firearms. Originating in ancient China as small hand cannons, guns eventually evolved into muzzle loaders, like those seen in Assassin’s Creed. IV: Black Flag, then revolvers, like most of the handguns in Red Dead Redemption, and eventually semi- automatic pistols, like the M1. Call of Duty and Medal of Honor. Police forces started equipping guns in the 1. When World War I came to a close, weapons manufacturers turned to the police to maintain their sales. Firearms and police forces have been closely connected ever since. Handguns are almost as old as video games themselves. What may have been the first video game handgun appeared in Taito’s 1. Western Gun, a Wild West- themed game where players shot at each other with revolvers. ![]() GameTrailers is your destination to see official trailers first. Powered by IGN, you can expect to see world-first exclusive gameplay and the hottest new tra. Other early examples of handguns include Nintendo’s 1. Western game Sheriff, Capcom’s 1. Gun. Smoke, and Konami’s 1. Sunset Riders. 1. Castle Wolfenstein, most notable for being the earliest stealth game, begins with a dying prisoner handing the player a gun they stole from the guards. In gameplay, the gun appears to be a handgun of some kind, most likely a Luger pistol. As games grew in sophistication and platforms grew in power, handguns became firmly entrenched in video game design. How Handguns Work. Whether it’s Doom’s classic pistol or Bloody Mary’s Smith & Wesson Model 2. The Wolf Among Us, handguns are ubiquitous video games. The appeal is obvious: handguns are small, portable, and easily concealed. When a villain reveals the gun hidden in his coat, it’s a moment of surprise. When a gunslinger draws on his opponent and wins the duel, it’s thrilling. It’s a lot harder to hide a rifle or draw a shotgun quickly. While there have been a staggering variety of handguns throughout the centuries, the most common types in games are revolvers and pistols, though the term “pistol” is often used synonymously with all handguns. Handguns start with a round, or cartridge, which consists of a case, the bullet, a primer, and the propellant. The cartridge is inserted into the chamber. Pulling the trigger causes the firing pin to strike the cartridge, which causes the primer to ignite the propellant. The expanding gases from the propellant push the bullet through the barrel of the gun, sending the bullet towards its target. The difference between a revolver and a pistol is in the way they chamber bullets. A revolver features a cylinder, which is usually loaded with six rounds, though there have been rare, unsuccessful variants over the years with as many as 3. When you pull the trigger, the cylinder rotates and the hammer pulls back. When you let go, the hammer strikes, firing the round. When you pull again, the cylinder rotates, and so on. Here’s a detailed video demonstrating the entire process. Pistols work differently. Rather than a cylinder, the pistol’s rounds are loaded into a magazine, which is usually inserted into the pistol’s grip. A round can’t be fired until it’s chambered, or transferred from the magazine to the chamber. Pull the trigger, fire a round, chamber a new round, pull the trigger again. If you’ve played a lot of games, especially shooters, you’re probably familiar with the basic pistol archetypes. From Half- Life to Gears of War to Destiny, revolvers are portrayed as slow- firing, powerful weapons, while pistols are portrayed as weaker but faster- firing. This is a myth, because plenty of things can hamper a revolver’s power, and in some cases revolvers can fire just as fast as pistols. Power has nothing to do with the way the round is chambered. A round’s power is determined largely by its kinetic force, and that force is determined by the round itself, based on the mass of the bullet and the power of the propellant. So why do shooters perpetuate these myths about how handguns work? How Handguns Work In Shooters. Most shooter design can be traced, in some way, back to Doom, id’s seminal 1. Doom cemented basic shooter weapon archetypes in video games: the pistol, the shotgun, the automatic rifle, and the rocket launcher. In Doom, the pistol fired a single shot, the shotgun fired multiple pellets at once, the plasma rifle and chaingun fired multiple shots in quick succession, and the rocket launcher fired a single shot that did explosive splash damage. Developers have been fond of progression systems, and Doom’s weapon- based progression was near perfect: start with the pistol, end up with the incredible plasma- firing BFG. In the 2. 4 years since Doom’s release, few developers have messed with the formula. Halo tried churn,where players had to constantly scavenge for weapons on the battlefield, and Borderlands went for a Diablo- style stat system. But most shooters all begin the same way: like Doom, they start with a handgun. As a result, handguns tend to be portrayed as weak starter weapons that you replace with more powerful shotguns or more accurate rifles. Some shooters, like Destiny or Borderlands, are based around stats; as you grow in power, you find guns with better stats, doing, say, 1. Others, like Hitman, give pistols the advantage of being concealable or quiet, making them preferable over more aggressive weaponry. But by and large handguns are starter weapons, meant to be suffered through until something better comes along. Video game weapons rarely match their real- world counterparts. In video games, shotguns tend to shoot confetti beyond three meters, and flamethrowers seem to be propane- based movie flamethrowers, which are designed to keep actors safe rather than behaving like their proper napalm- based counterparts. Handguns are no different: as the starting weapons, they tend to be weak, because they exist as gateway weapons that carry you along until you get to better weapons. But it doesn’t have to be this way. How Breaking The Rules Leads To Better Handguns. Handguns don’t need to be weak. Plenty of games contain unique takes on handguns that elevate them from starter weapons into some of the best weapons in shooter history. Titanfall 2 contains a level where you lose all your weapons, but you gain the smart pistol for the first time shortly after. What follows is a level that’s all about empowerment. Every other weapon in the game needs aiming, but the smart pistol locks on and one- shots enemies. This lets you wallrun without sacrificing your accuracy, making for an awesome escape sequence where you never stop running. Getting that pistol, in some ways, feels like the pinnacle of Titanfall 2’s campaign. Wolfenstein: The New Order’s pistol is no slouch, but it’s the only weapon in the game that can be silenced. This makes it a great choice if you’re trying to play stealthily. You can also dual- wield and auto- fire, adding to its versatility, but it shines in its unique role as a stealth tool. Since The New Order has plenty of stealth segments, the pistol holds its own. The Boltok, from the Gears of War series, is a legendary revolver. One of the Gears series best features is its gib system. Most enemies die as you would expect when they’re killed, but when the you headshot an enemy with the Boltok, his head practically explodes in a fountain of blood and viscera, accompanied by a satisfying splorch noise. The big secret to Gears special sauce is the way enemies react to its guns, and the Boltok creates some of the best reactions in the series. Halo: Combat Evolved’s M6. D seems like a regular pistol, but it’s got a nice 2. X scope on it, which isn’t a common feature on video game pistols. Later Halo games treat pistols more like the traditional weak starter weapon, even when you don’t actually start with a pistol, but the M6. D has high damage and can hold its own in a firefight. Heck, if you’re in the right position, the M6. D can take out Halo’s toughest enemies, hunters, with a single shot to their weak point. The M6. D feels amazing in part because it isn’t a hitscan weapon; there’s this split second of lag between firing and hitting that gives it a satisfying crunch that hitscan weapons in other games can’t replicate. Bungie didn’t stop there. ![]() Artist's Guide to Sketching by James Gurney. Thanks for telling us about the problem. Return to Book Page. James Gurney. Genre: Art. Guptill Pubns.Inc.,N.Y. Rating: 4.38. Download Artist's Guide to Sketching. to Sketching.pdf; Artist's Guide to Sketching.torrent;.The artist s guide to sketching Download Book The Artist S Guide To Sketching in PDF format. The Artist S Guide To Sketching Author : James Gurney. Artist's Guide to Sketching by James Gurney, 9780823003327, available at Book Depository with free delivery worldwide. Read Online: The Artist's Guide to. Sketching by James Gurney, Thomas Kinkade #PDF#Download> > > > Click. Here to Download / Read Online< < < < Read Online and Download The Artist's Guide to Sketching. Explore a new genre. Burn through a whole series in a weekend. Let. Grammy award- winning narrators transform your commute. Broaden your. horizons with an entire library, all yourown. THE BACKGROUND OF THIS BOOK - - In the early 1. Thomas Kinkade ("The Painter of Light"). James Gurney (Dinotopia) found themselves working as background. Ralph Bakshi/Frank. Frazetta sword & sorcery film. Fire and Ice. They had met in 1. Before they became established in their careers, they "sketched. America" as art hobos, hopping freight cars. Much of this. attitude and some of this biography made its way into the book, The. Artist's Guide to Sketching - - a book firmly committed to the idea. ABOUT THIS BOOK - - This is not a traditional "how to". The authors place a lot of emphasis on using the environment. Sketching isn't rendering. It is expressing feelings. TOPICS. COVERED IN THE BOOK - - Realities of sketching outdoors; materials. BOOK DETAILS - - hardback with. The Artist's Guide to Sketching by James. Gurney, Thomas Kinkade. Tags: The Artist's Guide to Sketching by James Gurney, Thomas. Kinkade Free download, audio books, books to read, good books to. The. Artist's Guide to Sketching by James Gurney, Thomas Kinkade books. Hydrogen - Wikipedia. Hydrogen, 1. HPurple glow in its plasma state. General properties. Pronunciation[1]HY- drə- jən. Appearancecolorless gas. Standard atomic weight(Ar)[7. Hydrogen in the periodic table. Leading a doomed company can often help a career by providing experience, insight, and contacts that lead to new opportunities, says professor Shikhar Ghosh. How do you define value? can you measure it? What are your products and services actually worth to customers? Remarkably few suppliers in business markets are able to. Atomic number(Z)1. Group, periodgroup 1, period 1. Blocks- block. Element category diatomic nonmetal. Electron configuration. Electrons per shell.
Physical properties. Colorcolorless. Phase(at STP)gas. Melting point. 13. K (−2. 59. 1. 6 °C, −4. F)Boiling point. 20. K (−2. 52. 8. 79 °C, −4. F)Density(at STP)0. Lwhen liquid (at m. Triple point. 13. K, 7. 0. 41 k. Pa. Critical point. 32. K, 1. 2. 85. 8 MPa. Heat of fusion(H2) 0. J/mol. Heat of vaporization(H2) 0. J/mol. Molar heat capacity(H2) 2. J/(mol·K)Vapor pressure. P (Pa)1. 10. 10. 01 k. T (K)1. 52. 0Atomic properties. Oxidation states−1, +1 (an amphoteric oxide)Electronegativity. Pauling scale: 2. Ionization energies. Covalent radius. 31±5 pm. Van der Waals radius. Miscellanea. Crystal structurehexagonal. Speed of sound. 13. C)Thermal conductivity. W/(m·K)Magnetic orderingdiamagnetic[4]Magnetic susceptibility−3. K)[5]CAS Number. 12. H2)History. Discovery. Henry Cavendish[6][7](1. Named by. Antoine Lavoisier[8](1. Main isotopes of hydrogen. Wikidata. Hydrogen is a chemical element with symbol H and atomic number 1. With a standard atomic weight of circa 7. Its monatomic form (H) is the most abundant chemical substance in the Universe, constituting roughly 7. Non- remnantstars are mainly composed of hydrogen in the plasma state. The most common isotope of hydrogen, termed protium (name rarely used, symbol 1. H), has one proton and no neutrons. The universal emergence of atomic hydrogen first occurred during the recombination epoch. At standard temperature and pressure, hydrogen is a colorless, odorless, tasteless, non- toxic, nonmetallic, highly combustiblediatomicgas with the molecular formula H2. Since hydrogen readily forms covalent compounds with most nonmetallic elements, most of the hydrogen on Earth exists in molecular forms such as water or organic compounds. Hydrogen plays a particularly important role in acid–base reactions because most acid- base reactions involve the exchange of protons between soluble molecules. In ionic compounds, hydrogen can take the form of a negative charge (i. H+. The hydrogen cation is written as though composed of a bare proton, but in reality, hydrogen cations in ionic compounds are always more complex. As the only neutral atom for which the Schrödinger equation can be solved analytically,[1. Hydrogen gas was first artificially produced in the early 1. In 1. 76. 6–8. 1, Henry Cavendish was the first to recognize that hydrogen gas was a discrete substance,[1. Greek, hydrogen means "water- former". Industrial production is mainly from steam reforming natural gas, and less often from more energy- intensive methods such as the electrolysis of water.[1. Most hydrogen is used near the site of its production, the two largest uses being fossil fuel processing (e. Hydrogen is a concern in metallurgy as it can embrittle many metals,[1. Properties. Combustion. Explosion of a hydrogen–air mixture. Hydrogen gas (dihydrogen or molecular hydrogen)[1. The enthalpy of combustion is −2. J/mol: [1. 7]2 H2(g) + O2(g) → 2 H2. O(l) + 5. 72 k. J (2. J/mol)[note 2]Hydrogen gas forms explosive mixtures with air in concentrations from 4–7. The explosive reactions may be triggered by spark, heat, or sunlight. The hydrogen autoignition temperature, the temperature of spontaneous ignition in air, is 5. C (9. 32 °F).[1. 8] Pure hydrogen- oxygen flames emit ultraviolet light and with high oxygen mix are nearly invisible to the naked eye, as illustrated by the faint plume of the Space Shuttle Main Engine, compared to the highly visible plume of a Space Shuttle Solid Rocket Booster, which uses an ammonium perchlorate composite. The detection of a burning hydrogen leak may require a flame detector; such leaks can be very dangerous. Hydrogen flames in other conditions are blue, resembling blue natural gas flames.[1. The destruction of the Hindenburg airship was a notorious example of hydrogen combustion and the cause is still debated. The visible orange flames in that incident were the result of a rich mixture of hydrogen to oxygen combined with carbon compounds from the airship skin. H2 reacts with every oxidizing element. Hydrogen can react spontaneously and violently at room temperature with chlorine and fluorine to form the corresponding hydrogen halides, hydrogen chloride and hydrogen fluoride, which are also potentially dangerous acids.[2. Electron energy levels. Depiction of a hydrogen atom with size of central proton shown, and the atomic diameter shown as about twice the Bohr model radius (image not to scale)The ground stateenergy level of the electron in a hydrogen atom is −1. V,[2. 1] which is equivalent to an ultraviolet photon of roughly 9. The energy levels of hydrogen can be calculated fairly accurately using the Bohr model of the atom, which conceptualizes the electron as "orbiting" the proton in analogy to the Earth's orbit of the Sun. However, the atomic electron and proton are held together by electromagnetic force, while planets and celestial objects are held by gravity. Because of the discretization of angular momentum postulated in early quantum mechanics by Bohr, the electron in the Bohr model can only occupy certain allowed distances from the proton, and therefore only certain allowed energies.[2. A more accurate description of the hydrogen atom comes from a purely quantum mechanical treatment that uses the Schrödinger equation, Dirac equation or even the Feynmanpath integral formulation to calculate the probability density of the electron around the proton.[2. The most complicated treatments allow for the small effects of special relativity and vacuum polarization. In the quantum mechanical treatment, the electron in a ground state hydrogen atom has no angular momentum at all—illustrating how the "planetary orbit" differs from electron motion. Elemental molecular forms. There exist two different spin isomers of hydrogen diatomic molecules that differ by the relative spin of their nuclei.[2. In the orthohydrogen form, the spins of the two protons are parallel and form a triplet state with a molecular spin quantum number of 1 ( 1⁄2+ 1⁄2); in the parahydrogen form the spins are antiparallel and form a singlet with a molecular spin quantum number of 0 ( 1⁄2– 1⁄2). At standard temperature and pressure, hydrogen gas contains about 2. The equilibrium ratio of orthohydrogen to parahydrogen depends on temperature, but because the ortho form is an excited state and has a higher energy than the para form, it is unstable and cannot be purified. At very low temperatures, the equilibrium state is composed almost exclusively of the para form. The liquid and gas phase thermal properties of pure parahydrogen differ significantly from those of the normal form because of differences in rotational heat capacities, as discussed more fully in spin isomers of hydrogen.[2. The ortho/para distinction also occurs in other hydrogen- containing molecules or functional groups, such as water and methylene, but is of little significance for their thermal properties.[2. The uncatalyzed interconversion between para and ortho H2 increases with increasing temperature; thus rapidly condensed H2 contains large quantities of the high- energy ortho form that converts to the para form very slowly.[2. The ortho/para ratio in condensed H2 is an important consideration in the preparation and storage of liquid hydrogen: the conversion from ortho to para is exothermic and produces enough heat to evaporate some of the hydrogen liquid, leading to loss of liquefied material. Catalysts for the ortho- para interconversion, such as ferric oxide, activated carbon, platinized asbestos, rare earth metals, uranium compounds, chromic oxide, or some nickel[3. Phases. Compounds. Covalent and organic compounds. While H2 is not very reactive under standard conditions, it does form compounds with most elements. Hydrogen can form compounds with elements that are more electronegative, such as halogens (e. F, Cl, Br, I), or oxygen; in these compounds hydrogen takes on a partial positive charge.[3. When bonded to fluorine, oxygen, or nitrogen, hydrogen can participate in a form of medium- strength noncovalent bonding with the hydrogen of other similar molecules, a phenomenon called hydrogen bonding that is critical to the stability of many biological molecules.[3. Many, if not most, cell phones these days offer built-in music players. In many cases, you can download music to your cell phone over the air through your. Motorola Moto Z Droid Edition. Apple® i. Phone® 8 Plus. Apple® i. Phone® 8. Apple® Watch Series 3.
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The Almighty Janitor trope as used in popular culture. Some works of fiction live and die on rankings. The characters have their own power hierarchy, but. Narrative - Wikipedia. A narrative or story is a report of connected events, real or imaginary, presented in a sequence of written or spoken words, or still or moving images,[1][2] or both. The word derives from the Latin verb narrare, "to tell", which is derived from the adjective gnarus, "knowing" or "skilled".[3]Narrative can be organized in a number of thematic or formal categories: non- fiction (such as definitively including creative non- fiction, biography, journalism, transcript poetry, and historiography); fictionalization of historical events (such as anecdote, myth, legend, and historical fiction); and fiction proper (such as literature in prose and sometimes poetry, such as short stories, novels, and narrative poems and songs, and imaginary narratives as portrayed in other textual forms, games, or live or recorded performances). Narrative is found in all forms of human creativity, art, and entertainment, including speech, literature, theatre, music and song, comics, journalism, film, television and video, video games, radio, gameplay, unstructured recreation, and performance in general, as well as some painting, sculpture, drawing, photography, and other visual arts, as long as a sequence of events is presented. ![]() Several art movements, such as modern art, refuse the narrative in favor of the abstract and conceptual. Oral storytelling is the earliest method for sharing narratives. During most people's childhoods, narratives are used to guide them on proper behavior, cultural history, formation of a communal identity, and values, as especially studied in anthropology today among traditional indigenous peoples.[5]Narratives may also be nested within other narratives, such as narratives told by an unreliable narrator (a character) typically found in noir fiction genre. An important part of narration is the narrative mode, the set of methods used to communicate the narrative through a process narration (see also "Narrative Aesthetics" below). Along with exposition, argumentation, and description, narration, broadly defined, is one of four rhetorical modes of discourse. More narrowly defined, it is the fiction- writing mode in which the narrator communicates directly to the reader. Human nature[edit]Owen Flanagan of Duke University, a leading consciousness researcher, writes, "Evidence strongly suggests that humans in all cultures come to cast their own identity in some sort of narrative form. We are inveterate storytellers."[6] Stories are an important aspect of culture. Many works of art and most works of literature tell stories; indeed, most of the humanities involve stories. Stories are of ancient origin, existing in ancient Egyptian, ancient Greek, Chinese and Indian cultures and their myths. Stories are also a ubiquitous component of human communication, used as parables and examples to illustrate points. Storytelling was probably one of the earliest forms of entertainment. As noted by Owen Flanagan, narrative may also refer to psychological processes in self- identity, memory and meaning- making. Semiotics begins with the individual building blocks of meaning called signs; and semantics, the way in which signs are combined into codes to transmit messages. This is part of a general communication system using both verbal and non- verbal elements, and creating a discourse with different modalities and forms. In On Realism in Art. Roman Jakobson argues that literature exists as a separate entity. He and many other semioticians prefer the view that all texts, whether spoken or written, are the same, except that some authors encode their texts with distinctive literary qualities that distinguish them from other forms of discourse. Nevertheless, there is a clear trend to address literary narrative forms as separable from other forms. This is first seen in Russian Formalism through Victor Shklovsky's analysis of the relationship between composition and style, and in the work of Vladimir Propp, who analysed the plots used in traditional folk- tales and identified 3. This trend (or these trends) continued in the work of the Prague School and of French scholars such as Claude Lévi- Strauss and Roland Barthes. It leads to a structural analysis of narrative and an increasingly influential body of modern work that raises important epistemological questions: What is text? What is its role (culture)? How is it manifested as art, cinema, theater, or literature? Why is narrative divided into different genres, such as poetry, short stories, and novels? Literary theory[edit]In literary theoretic approach, narrative is being narrowly defined as fiction- writing mode in which the narrator is communicating directly to the reader. Until the late 1. Iliad and Paradise Lost, and poetic drama like Shakespeare). Most poems did not have a narrator distinct from the author. But novels, lending a number of voices to several characters in addition to narrator's, created a possibility of narrator's views differing significantly from the author's views. With the rise of the novel in the 1. It has been proposed that perspective and interpretive knowledge are the essential characteristics, while focalization and structure are lateral characteristics of the narrator.[according to whom?]Types of narrators and their modes[edit]A writer's choice in the narrator is crucial for the way a work of fiction is perceived by the reader. There is a distinction between first- person and third- person narrative, which Gérard Genette refers to as intradiegetic and extradiegetic narrative, respectively. Intradiagetic narrators are of two types: a homodiegetic narrator participates as a character in the story. Such a narrator cannot know more about other characters than what their actions reveal. A heterodiegetic narrator, in contrast, describes the experiences of the characters that appear in the story in which he or she does not participate. Most narrators present their story from one of the following perspectives (called narrative modes): first- person, or third- person limited or omniscient. Generally, a first- person narrator brings greater focus on the feelings, opinions, and perceptions of a particular character in a story, and on how the character views the world and the views of other characters. If the writer's intention is to get inside the world of a character, then it is a good choice, although a third- person limited narrator is an alternative that does not require the writer to reveal all that a first- person character would know. By contrast, a third- person omniscient narrator gives a panoramic view of the world of the story, looking into many characters and into the broader background of a story. A third- person omniscient narrator can be an animal or an object, or it can be a more abstract instance that does not refer to itself. For stories in which the context and the views of many characters are important, a third- person narrator is a better choice. However, a third- person narrator does not need to be an omnipresent guide, but instead may merely be the protagonist referring to himself in the third person (also known as third person limited narrator). Multiple narrators. A writer may choose to let several narrators tell the story from different points of view. Then it is up to the reader to decide which narrator seems most reliable for each part of the story. It may refer to the style of the writer in which he/she expresses the paragraph written. See for instance the works of Louise Erdrich. William Faulkner's As I Lay Dying is a prime example of the use of multiple narrators. Faulkner employs stream of consciousness to narrate the story from various perspectives. In Indigenous American communities, narratives and storytelling are often told by a number of elders in the community. In this way, the stories are never static because they are shaped by the relationship between narrator and audience. Thus, each individual story may have countless variations. Narrators often incorporate minor changes in the story in order to tailor the story to different audiences.[9]Aesthetics approach[edit]Narrative is a highly aesthetic art. Thoughtfully composed stories have a number of aesthetic elements. What Angry Big City Drivers Can Learn From The Rest Of Us. I grew up in Northeast Ohio, where driving, like in most of the non- urbanized and subway- ified world, is just a part of life, like shitting. And—not dissimilar to Midwestern defecation, come to think of it—Ohioans tend to drive very slowly, while honking is mostly unheard of and speed limits are generally abided by. That’s in large part because police at every level of government, with little else to do, enthusiastically police the behavior of drivers, whether for speed, or one’s turn signals, or merely having plates that are close to expiring. This is not the case in New York City, where I now live, where speed limits are generally ignored and horns are frequently employed and the police don’t really care how you drive, unless they’re out on some kind of targeted enforcement or you’ve just killed someone or you are massively inconveniencing others. I’ve received two moving violations in NYC, the first, many years ago, for blocking the box in Manhattan, and, the second, last summer, for driving 2. Grand Central Parkway. The ticketing officer in the latter case explained to me then that 1. All right. And while NYC driving is all very exciting, I’m here to propose that city drivers could learn some lessons from their flyover counterparts. Namely: chill the fuck out. When you’re not on the track, driving isn’t about winning. Let’s start with when you’re allowed to honk, which is really only under a few circumstances. To be specific: if someone is about to die, you’re allowed to honk for as long and as loud as you want. If the driver in front of you hasn’t noticed that a red light has turned green, you’re allowed to give the horn a tap, and possibly two. A nice, polite little tap. A reminder beep. Otherwise: No. If you’re sitting in traffic and you can’t really see why, do not honk your horn. If you’re annoyed that a taxi, which is in the midst of either picking up or dropping off a passenger, is temporarily blocking your way, do not honk your own. If you’re behind someone, and they’re being indecisive about which way to turn—and are clearly just people in this world like you or I, trying to figure out a few things in the proverbial fog—do not honk your horn. Take a breath instead. If you’re driving down a narrow one- way road, and a truck, which is making a delivery, is blocking said road, and it looks like it’ll be awhile, do not honk your horn. Calmly put your car in reverse, back out of the street, and try a different street. You’ll be fine. Now, let’s talk about highway driving, which in the city is usually one of three things: sitting in a very large elevated parking lot; the magical hours between between 2 and 5 a. This mostly happens on the weekend.)Here is what you do during those times, when you’re cruising along with the flow of traffic and you’re being cut off while other drivers speed past and trucks bear down on your rear: You keep driving like a normal person. The same rules also generally apply to street driving in NYC, but because of a host of limitations—lots of one- way streets, street lights, speed cameras, lots of traffic at all hours—such issues don’t ordinarily come up. Suffice to say: There are a lot of drivers in New York who are eager to prove themselves, who drive very fast and create dangerous situations for everyone. The best thing to do is to let them pass and move on with your life. If they’re in it to win it, you should let them, because you are not in it to win it. You’re too old, and with a declining appetite for bullshit. You’re just trying to get to the beach. Here’s a story: once, when I was driving on Bedford Avenue in Williamsburg, a man in an SUV cut me off, and I gave him the finger, and might have also said fuck you a few times. All of which felt like standard blowing- off- of- steam in NYC, until that man then drove his SUV in front of me, stopped, exited his vehicle, and challenged me to a fight. Spoiler: Cooler heads eventually prevailed, and we did not fight, even if, for a minute, he meant it. Here’s another story: once when I was in Central Park, I saw a man driving a Lexus park his car in the middle of the intersection at Central Park South and Seventh Avenue, exit his still- running vehicle, and chase a cyclist on foot, shouting obscenities and threatening bodily harm. The man did not catch the cyclist. Here’s one more story: Three weeks ago, in Sunnyside, Queens, where I live—not ordinarily the scene of much road rage—a man left his vehicle and repeatedly kicked a black cab, enough to leave several dents in the body, all over the offense of honking too much and rushing the driver at a green light. I bring up these stories only to say that, while there are unhinged drivers on the streets everywhere in the world, there might be a higher density of unhinged drivers on the streets of New York, not in small part because unless driving is part of your occupation you have to be a little unhinged to drive a car here to begin with. Those that drive for a living, you’ll find, like bus drivers and truck drivers and taxi drivers (well, maybe not all taxi drivers, since part of taxi driving, when a fare is aboard, is theater, a combination of honking and cursing that shows the paying rider that, really, the driver is doing all they can to get the fare where they’re going quickly) are some of the most placid on the roads. They’ve seen more than you have, and know the value of keeping calm and carrying on. The other night, I parked my car near a fire hydrant. Was it too close? I don’t know. Probably! In New York City, it’s illegal to park within 1. Honda Fit. I was definitely in the ballpark, but, like with a lot of car rules in the city—including mine above—it’s a bit subjective. Take them with a grain of salt. Do everything in moderation, including moderation. And once you know the rules, feel free to break them, or at least bend them. Sometimes the catharsis of your horn is more important than keeping your composure. My parking ticket, for one, never materialized. Above all else, calm down. You’ll get where you’re going. We did in Ohio every day. Download Cracked i. OS Games and Apps for Free Without Jailbreak. Cracked mac. OS Games, Apps. Books for i. Phone, i. Pad and mac. OS - Latest Apps. Free Download Android Apps and Games Apk Files. Are your feels uncomfortable, when your android mobile and tablet are very slow in downloading media files, and other stuff? Then don’t worry, we have. Best Cracked App Downloader Cydia Ipa ImpactorWith this IPA app you can twisted your iPhone or iPad into a Music instruments and you can. IphoneIPaStore is a beautifully crafted blogging website for iPhone and. Learn how to Install Cracked IPA Apps on iPhone or iPad with. You can get this from Cydia repos like SinfuliPhone or. your cracked app will appear on your. 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